Alkaline Water Electrolyser (AWE)
Alkaline Water Electrolyser (AWE) is a mature hydrogen production technology, characterised by its reliance on an alkaline electrolytic solution. The electrolyser consists of two electrodes (anode and cathode) separated by a diaphragm containing the alkaline electrolytic solution, typically potassium hydroxide or sodium hydroxide. The liquid electrolyte allows exchange of ions between the anode and cathode, resulting in hydrogen production at the cathode. A schematic of the AWE technology is illustrated in Figure X. AWEs provide a cost-effective, durable, and simple solution for green hydrogen production, making them a staple in industrial applications. The biggest advantage of AWEs is their scalability, supporting both small- and large-scale hydrogen production.
The AWE market was value at £116m in 2024, with an estimated market size of £172m by 2032. Government policies and a global shift towards sustainable energy solutions have spurred rapid market growth for
green hydrogen production technologies. However, when compared to other electrolysers, the AWE market projections are significantly smaller. This is due to their inability to handle dynamic load fluctuations,
making them unsuitable for integration with renewable energy sources, such as wind and solar energy. Additionally, AWEs exhibit a much lower efficiency than other electrolyser technologies, increasing operational
costs. The presence of the highly alkaline solution also poses a significant challenge, as this may cause corrosion and rapid degradation. Any leakage of the strong alkaline electrolyte will damage the metal
catalyst and will significantly increase replacement and operational costs. These challenges need to be addressed before AWEs can compete with other electrolyser technologies
Alkaline Water Electrolyser (AWE)
Electrodes
- Long-term stability of anode materials
- Advanced surface engineering approaches effectively addressed issues concerning catalyst degradation and passivation
- Fortify the durability of anode materials under the challenging alkaline conditions inherent to water electrolysis
Catalyst
- Precise design of catalysts at the atomic level to achieve well-balanced water splitting kinetics
- Non-metal catalysts
Alkaline electrolyte solutions
- Higher ionic conductivity
- Less electrode degradation
- Good solubility and conductivity properties
- The optimal electrolyte concentration
- Maintain adequate conductivity while being less corrosive
- Develop membrane systems with ion-solvating properties featuring improved alkaline stability and robust structural chemistries
- Separator
- Hydrogen permeation
- Alkaline stability
- Low ionic resistance
- High bubble point pressure
- Safety
- The minimum load of the electrolyzer and the potential damage to electrodes when the electrolyzers are shut down
- Cost
Academic Capability Mapping
Word cloud
The word-cloud of the primary and secondary keywords is presented for the Alkaline Water Electrolyser (AWE) technology. These keywords were used as the input to Scopus for the purpose of the Academic Capability Mapping. The analysis underscores key research areas like electrocatalysis and alkaline electrolyte, while highlighting reliance on Nickel.
Documents by Country
The number of papers published worldwide pertaining to Alkaline Water Electrolysers (AWE) since the year 2000, divided into three decades. Only the top 10 countries are displayed. It is interesting to note that the UK is not in the top 10 countries researching AWE as a potential route to green hydrogen production, despite the maturity of the technology. The UK ranks at number 12 globally in AWE research
Documents by Author (2000 – 2025)
Prominent UK academics and their affiliation is showcased. The y-axis represents the H-index of the authors, while the x-axis illustrates the number of papers published. It can be clearly seen that while the UK authors may have high H-index’s, the number of papers in the field of AWE are less than 7, indicating a shift towards alternative electrolyser technologies.
Documents by Affiliation
The number of papers published by affiliation in the UK since the year 2000 are showcased. Newcastle University leads the way with the most publications, closely followed by the University of Strathclyde. The figure specifically highlights the top 10 UK institutions in the field of Alkaline Water Electrolysers, providing a definite ranking list of universities with excellent expertise in the AWE technology.
Alkaline Water Electrolyser (AWE) – Delphi Survey Analysis
Participant Identifiers
Industry Collaboration
Confidence Level
Country Affiliation
Key Performance Indicators
Key technical target predictions were provided by the participants, expected to be achieved by 2030.
Challenges
The participants were provided with several options and were asked to rank these options from 0 (least critical) to 6 (most critical). They were also provided with a text option to suggest additional challenges.
Additional Challenges and Developmental Needs
- H2 electrode
- O2 electrode
- Fluorine-free membrane
- Highly compact stack
- Sealing mechanisms
- Material development
- Corrosion stability
Key Component Challenges
Stack and System Challenges
Alkaline Water Electrolyser System Integration
- Balancing intermittent renewable generation
- Grid stability through adjustable hydrogen production rates
- Peak regulation and voltage regulation
- Energy conversion and storage
- Desalination
- Green ammonia production
- Biomass production
- Solar, wind, or biomass facilities supplying electricity
- Infrastructure to ensure a consistent water supply
- Bulk power grid
- Power quality
- Chemical Industry
- Steel Industry
- Green ammonia production
- Fuel cell systems